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Structure of the product formed via Cu(I)-promoted oxidative dimerization ofexo-8-ethynylpentacyclo[5.4.0.02,6.03,10.05.9]undecan-endo-8-ol
Authors:Simon G. Bott  Alan P. Marchand  L. Kathleen Talafuse  D. Rajagopal
Affiliation:(1) Department of Chemistry, University of North Texas, 76203 Denton, Texas
Abstract:
The structure consists of two acetyl-substituted PCU cages linked by a diyne fragment. The conformation about the linker is midway between staggered and eclipsed, and the acetyl groups are somewhat distorted due to the proximity to the bulky cage units.
Keywords:Crystal structure  diyne  oxidative dimerization
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