Structure of the product formed via Cu(I)-promoted oxidative dimerization ofexo-8-ethynylpentacyclo[5.4.0.02,6.03,10.05.9]undecan-endo-8-ol |
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Authors: | Simon G. Bott Alan P. Marchand L. Kathleen Talafuse D. Rajagopal |
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Affiliation: | (1) Department of Chemistry, University of North Texas, 76203 Denton, Texas |
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Abstract: | ![]() The structure consists of two acetyl-substituted PCU cages linked by a diyne fragment. The conformation about the linker is midway between staggered and eclipsed, and the acetyl groups are somewhat distorted due to the proximity to the bulky cage units. |
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Keywords: | Crystal structure diyne oxidative dimerization |
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