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Evaluation of the Wagner irreversible constitutive equation
Authors:Dr. J. S. Vrentas  C. M. Vrentas  D. C. Venerus
Affiliation:(1) Department of Chemical Engineering, The Pennsylvania State University, University Park, Pennsylvania, USA;(2) Department of Chemical Engineering, Illinois Institute of Technology, Chicago, Illinois, USA
Abstract:
A constitutive equation based on the concept of the irreversibility of the rupture of a polymer network has been previously proposed as an improvement to the K-BKZ model. This Wagner irreversible constitutive equation is evaluated here using data from double-step shear strain experiments. It is shown that the Wagner irreversible model does not in general provide good predictions when a comprehensive set of deformation histories is considered.
Keywords:K-BKZ model  Wagner irreversible model  double-step experiment  irreversibility  flow reversal
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