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The charge-transfer absorption band of Eu3+ in oxides
Authors:H.E. Hoefdraad
Affiliation:Department of Solid State Chemistry, Physical Laboratory, University of Utrecht, Sorbonnelaan 4, Utrecht, The Netherlands
Abstract:
The position of the charge-transfer band of Eu3+ in the absorption spectra of a number of oxides is discussed. It is shown that this position is more or less fixed in octahedral VI coordination and that it varies in VIII and XII coordinations as a function of the effective ionic radius of the relevant host lattice ion.
Keywords:
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