A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex |
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| Authors: | Cheng Jian-Kai Chen Yu-Biao Wu Ling Zhang Jian Wen Yi-Hang Li Zhao-Ji Yao Yuan-Gen |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China. |
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| Abstract: | The solvothermal reaction of CuCl(2).2H(2)O with pyridine-4-thiol and ethanol yielded a novel photoluminescent 3-D polymeric complex with an interesting decorated diamondoid network that is constructed of decanuclear copper(I) cluster units and mu(4)-Cl ligands. The in situ generation of CuSO(4).5H(2)O implies the spontaneous occurrence of desulfurization and redox reactions in the present system. |
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