Synthetic applications of the carbanion generated from 4,4,4-trifluorobutan-2-one |
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| Authors: | Tsuneyoshi Tominaga |
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| Institution: | Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku Yokohama 226-8501, Japan |
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| Abstract: | Synthetic routes for α-trifluoromethylated carbonyl compounds based on the aldol reaction of silylenol ether and the palladium(0) catalyzed reaction using by 4,4,4-trifluorobutan-2-one are described. |
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| Keywords: | α-Trifluoromethylated carbonyl compounds β-Fluorocarbanion Palladium(0) |
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