Interaction of tetrabutylammonium octahydrotriborate with aluminum chloride. A new method for the preparation of tetraborane(10) |
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| Authors: | L V Titov L V Zhemchugova |
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| Institution: | (1) Institute of New Chemical Problems, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | Interaction of Bu4NB3H8 with AlCl3 at 45–50 °C results in the formation of BH4
– and unstable borane B2H4, which is converted into a mixture of B4H10, B5H9, and B2H6. This reaction can be used for the preparation of tetraborane(10). |
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| Keywords: | octa hyd rot ribo rate Lewis acids tetrahydroborate diborane(6) tetraborane(10) pentaborane(9) |
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