| 完美骨架全硅β沸石性质研究 |
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| 引用本文： | 宋茂莹,王喜庆,钱斌,曾宇,龙英才.完美骨架全硅β沸石性质研究[J].化学学报,2002,60(3):451-456. |
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| 作者姓名： | 宋茂莹 王喜庆 钱斌 曾宇 龙英才 |
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| 作者单位： | 复旦大学化学系,上海,200433 |
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| 基金项目： | 国家自然科学基金(No .2 0 0 730 10 )，教育部博士点基金资助项目 |
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| 摘 要： | 运用热分析技术研究胺类、烷烃类、芳香烃类、醇类在具完美骨架的合成得到 的全硅β沸石中的脱附行为，测定亲和性指娄A_T值和负载量。发现烷烃类、胺类 、芳香族化合物都对全硅β沸石骨架表现出亲和性，而醇类由于羟基的存在表现出 对骨架的憎性，结合吸附热等数据讨论了各类吸附质与骨架相互作用（主／客体相 互作用）的性质。
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| 关 键 词： | 硅 沸石 热分析 吸附 胺 烷烃 芳香族化合物 相互作用 |
| 修稿时间： | 2001年7月25日 |
Studies on Properties of Pure-silica β Zeolite Ⅱ. Adsorption/Desorption Behavior and Isosteric Heat of Organic Adsorbates |
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| SONG,Mao-Ying WANG,Xi-Qing QIAN,Bin ZENG,Yu LONG,Ying-Cai.Studies on Properties of Pure-silica β Zeolite Ⅱ. Adsorption/Desorption Behavior and Isosteric Heat of Organic Adsorbates[J].Acta Chimica Sinica,2002,60(3):451-456. |
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| Authors: | SONG Mao-Ying WANG Xi-Qing QIAN Bin ZENG Yu LONG Ying-Cai |
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| Institution: | Department of Chemistry, Fudan University.Shanghai(200433) |
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| Abstract: | The adsorption/desorption behaviors of 17 organic compounds on synthetic pure silica BEA type zeolite were investigated by means of TG/DTG/DTA analysis. The organics used as the adsorbates were alkanes, aromatics, alcohols, and alkylamines. A T value, the affinity index determined by DTG was used to characterize the interaction between the organic adsorbates and the perfect framework of the zeolite. The hydrophobic framework of the zeolite shows stronger affinity to the organic molecules containing amino and alkyl groups than those with hydroxyl groups. The nature of the sorbate/framework can be identified from the A T values, isosteric heat and interaction energy. |
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| Keywords: | SILICON ZEOLITE THERMAL ANALYSIS ADSORPTION AMINES ALKANE AROMATIC COMPOUNDS INTERACTIONS |
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