Interference effects in natural circular dichroism spectra |
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| Authors: | Aage E. Hansen |
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| Affiliation: | Department of Physical Chemistry, H.C. Ørsted Institute, University of Copenhagen, DK-2100 Copenhagen, Denmark |
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| Abstract: | ![]()
It is shown that Fano-type interference between a discrete (e.g. Rydberg) transition and a continuous (e.g. valence shell) transition can lead to natural circular dichroism line shapes which deviate significantly from simple superposition. The results are illustrated for a chiral molecule of C2 symmetry. |
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