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Adsorption and photochemical behaviors of the novel cationic xanthene derivative on the clay surface |
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| Authors: | Yuta Ohtani Yohei Ishida Yuka Ando Hiroshi Tachibana Tetsuya Shimada Shinsuke Takagi |
| Affiliation: | 1. Department of Applied Chemistry, Graduate Course of Urban Environmental Sciences, Tokyo Metropolitan University, Minami-ohsawa 1-1, Hachioji-shi, Tokyo 192-0397, Japan;2. Japan Society for the Promotion of Science (PD), Ichibancho, Chiyoda-ku, Tokyo 102-8471, Japan;3. Center for Artificial Photosynthesis, Minami-ohsawa 1-1, Hachioji-shi, Tokyo 192-0397, Japan |
| Abstract: | Novel tetra-cationic xanthene derivative (Flu) was synthesized. Its adsorption and photochemical behaviors on the clay surface were investigated. Fluorescence quantum yield (?f) and fluorescence lifetime were 0.50 and 2.9 ns for Flu/clay complex. ?f of Flu was enough high (>0.1) even at high density conditions (0.080 molecules nm−2). It is supposed that the strong interaction between clay and Flu by the ‘Size-Matching Effect’ realizes the highly emissive clay complexes at high density adsorption condition by a suppression of a molecular aggregation, which tends to decrease the photochemical activity. |
| Keywords: | Xanthene Clay Organic/inorganic complex Adsorption Size-Matching Effect |
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