Bromamine-T as an efficient amine source for Sharpless asymmetric aminohydroxylation of olefins |
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| Authors: | Arun Jyoti Borah Prodeep Phukan |
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| Institution: | Department of Chemistry, Gauhati University, Guwahati 781014, Assam, India |
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| Abstract: | Asymmetric aminohydroxylation of various olefins was carried out using bromamine-T as nitrogen source in the presence of (DHQ)2PHAL ligand. The new nitrogen source has been found to be effective in terms of yield and reaction time. The optical purities of the products could be obtained with up to 99% ee. |
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| Keywords: | Sharpless asymmetric aminohydroxylation Bromamine-T Potassium osmate (DHQ)2PHAL Olefin |
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