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Design and synthesis of a new fluorescent tripod for chemosensor applications
Authors:Mohammad S.I. Makki  Desislava Staneva  Tariq R. Sobahi  Paula Bosch  Reda M. Abdel-Rahman  Ivo Grabchev
Affiliation:1. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia;2. University of Chemical Technology and Metallurgy, 1756 Sofia, Bulgaria;3. Institute of Science and Technology of Polymers, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain;4. Sofia University “St. Kliment Ohridski”, Faculty of Medicine, 1407 Sofia, Bulgaria
Abstract:A new yellow-green fluorescent tripod based 1,8-naphthalimide has been synthesized and characterised. Its photophysical properties have been investigated in organic solvents of different polarity. The effect that the metal ions (Cd2+, Co2+, Zn2+, Mn2+, Mg2+, Ni2+, Pb2+, Cu2+, Ba2+, Fe3+ and Ag+) produce upon the fluorescent intensity of acetonitrile solutions of the tripod has been discussed viewing its potential applications as a detector for metal cations. The influence of protons on the fluorescence intensity of the tripod in DMF and methanol–water (1:4 v/v) solutions has also been investigated.
Keywords:Tripod   1,8-Naphthalimide   Sensor   Metalions   pH
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