Pd-catalyzed aerobic direct olefination of polyfluoroarenes |
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Authors: | Chun-Yang He Feng-Ling Qing Xingang Zhang |
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Affiliation: | 1. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China;2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China |
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Abstract: | The first example of Pd-catalyzed aerobic direct olefination of polyfluoroarenes has been developed. The reaction makes use of molecular O2 as terminal oxidant, and provides a cost-efficient and environmentally benign access to polyfluoroarene–alkene structures that are of interest in life and material sciences. |
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