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A rapid and convenient synthesis of gem-bis(dithiocarbamate) derivatives from primary aliphatic amines,carbon disulfide,and aromatic aldehydes using boron trifluoride-diethyl etherate |
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| Authors: | Firouzeh Nemati Ali Ghorbani Gharjeh Ghiyaei Behrouz Notash Mojtaba Hajiloo Shayegan Vahid Amani |
| Institution: | 1. Department of Chemistry, Semnan University, Semnan, Iran;2. Chemistry Department, Shahid Beheshti University, G. C., Evin, Tehran 1983963113, Iran;3. Department of Chemistry, Sharif University of Technology, PO Box 11465-9516, Iran;4. Department of Chemistry, Shahre-rey Branch, Islamic Azad University, Tehran, Iran |
| Abstract: | An efficient route for the synthesis of gem-bis(dithiocarbamate) derivatives is developed using dithiocarbamic acid salts generated from primary aliphatic amines and CS2. The method offers high yields, employs mild reaction conditions, and demonstrates excellent functional group compatibility. The structures of the products were confirmed spectroscopically and by X-ray analysis. |
| Keywords: | Dithiocarbamic acid salt Primary aliphatic amine Carbon disulfide Boron trifluoride-diethyl etherate |
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