Reaction of α,α,ω-trichloroalkenes with 1,1,1-trichloroethane and 1,1,1,3-tetrachloropropane,accompanied by rearrangement of radicals |
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Authors: | N V Kruglova R Kh Freidlina |
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Institution: | (1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions In the reaction of CCl3CH3 with CCl2=CHCH2CH2CH2Cl, and of CCl3CH2CH2Cl with CCl2= CHCH2Cl, initiated by Fe(CO)5+DMF, the main addition products are respectively compounds of structure HCCl2CH(CCl2CH3)CH2CH2CHCl2 and HCCl2CH(CCl2CH2CHCl2)CH2C1. The formation of these compounds was explained by the isomeriza'tion of the radical-adducts CCl2CH(CCl2CH3)CH2CH2CH2Cl and CCl2CH(CCl2CH2CH2Cl)CH2Cl, with migration of a hydrogen atom from the CH2Cl groups found in the 5 position to the radical center.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1857–1861, August, 1980. |
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