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First emission studies of Tc2X8(2-) systems (X = Cl, Br) |
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| Authors: | Briggs Breeze N McMillin David R Todorova Tanya K Gagliardi Laura Poineau Frederic Czerwinski Kenneth R Sattelberger Alfred P |
| Institution: | Department of Chemistry, Purdue University, West Lafayette, IN 47907-2084, USA. |
| Abstract: | The emission spectra of the solids n-Bu(4)N](2)Tc(2)X(8) (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the (1)δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime. |
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