Rate constant for the reaction of OH radicals with CH3C(O)Cl determined by direct kinetic method期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Rate constant for the reaction of OH radicals with CH₃C(O)Cl determined by direct kinetic method

Authors:	Rebeka Nádasdi István Szilágyi Gergely Kovács Sándor Dóbé Tibor Bérces Ferenc Márta

Affiliation:	(1) Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary;(2) Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary;(3) Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary;(4) Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary;(5) Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary;(6) Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary

Abstract:	Summary The fast flow technique with OH resonance fluorescence detection has been applied at T = 298 ± 2 K to study the kinetics of the overall reaction: H + CH₃C(O)Cl → products (1) A rate constant value of k₁ = (1.02 ± 0.12) x 10¹⁰ cm³ mol^-1 s^-1 has been determined which is the first direct kinetic parameter reported for reaction (1) in the literature (the error given refers to 2σ accuracy).

Keywords:
本文献已被 SpringerLink 等数据库收录！