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An activated equivalent of lactide toward organocatalytic ring-opening polymerization
Authors:Thillaye du Boullay Olivier  Marchal Emmanuel  Martin-Vaca Blanca  Cossío Fernando P  Bourissou Didier
Affiliation:Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 09, France.
Abstract:
The alpha-lactone equivalent lacOCA exhibits remarkable reactivity compared with lactide in nucleophile-catalyzed ROP. PLAs of controlled molecular weights and narrow polydispersities are typically obtained under mild conditions using DMAP and various protic initiators.
Keywords:
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