An activated equivalent of lactide toward organocatalytic ring-opening polymerization |
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Authors: | Thillaye du Boullay Olivier Marchal Emmanuel Martin-Vaca Blanca Cossío Fernando P Bourissou Didier |
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Affiliation: | Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 09, France. |
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Abstract: | The alpha-lactone equivalent lacOCA exhibits remarkable reactivity compared with lactide in nucleophile-catalyzed ROP. PLAs of controlled molecular weights and narrow polydispersities are typically obtained under mild conditions using DMAP and various protic initiators. |
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