| 双（1,2—丙二胺）合铜的TCNQ盐的合成与光谱研究 |
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| 引用本文： | 谢斌.双（1,2—丙二胺）合铜的TCNQ盐的合成与光谱研究[J].化学研究与应用,1997,9(2):147-150. |
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| 作者姓名： | 谢斌 |
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| 作者单位： | 四川轻化工学院基础部 |
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| 摘 要： | 合成了导电性ＴＣＮＱ盐Ｃｕ（ｐｎ）２（ＴＣＮＱ）ｎ（ｎ＝２和３，ｐｎ＝１，２－丙二胺，ＴＣＮＱ＝７，７，８，８－四氰基对苯二醌二甲烷）。红外光谱、电子光谱和Ｘ－光电子能谱研究表明ＴＣＮＱ盐中存在ＴＣＮＱ°和ＴＣＮＱ－，ＴＣＮＱ°与ＴＣＮＱ－之间发生了部分电子转移，致使铜呈混合价态。它们的粉末室温电导率为１．１×１０－５～２．４×１０－６ｏｈｍ－１ｃｍ－１。
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| 关 键 词： | TCNQ 红外光谱 电子光谱 电导率 丙二胺 铜 |
PREPARATION AND SPECTROSCOPIC STUDIES OF TCNQ SALTS OF COPPER COMPLEX WITH PROPYLENEDIAMINE |
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| Xie,Bin.PREPARATION AND SPECTROSCOPIC STUDIES OF TCNQ SALTS OF COPPER COMPLEX WITH PROPYLENEDIAMINE[J].Chemical Research and Application,1997,9(2):147-150. |
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| Authors: | Xie Bin |
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| Abstract: | The TCNQ salts Cu(pn) 2(TCNQ)n(n=2 and 3,pn=propylenediamine,TCNQ=7,7,8-tetracyanoquinodimethane) have been prepared.The infrared and electronic absorption and X ray photoeletronic spectra show that there are TCNQ 0 and TCNQ - in the TCNQ salts and the one dimensional molecular column of TCNQ has been formed;the partial electron transfer takes place between copper and TCNQ. |
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| Keywords: | TCNQ Infaraed spectra electronic absorption spectra X ray photoeletronic spectra conductivity |
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