| Synthesis and Crystal Structure of 1,4,Bis-（benztriazol-1-ylmethyl）-2,3,5,6-tetramethylbenzene |
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| 引用本文： | CAI Yue-Penga,b①HE Guang-PingaCAI YicZHANG Chia SU Cheng-Yongb KANG Bei-Shengb a.Synthesis and Crystal Structure of 1,4,Bis-（benztriazol-1-ylmethyl）-2,3,5,6-tetramethylbenzene[J].结构化学,2005,24(3):279-282. |
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| 作者姓名： | CAI Yue-Penga b①HE Guang-PingaCAI YicZHANG Chia SU Cheng-Yongb KANG Bei-Shengb a |
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| 作者单位： | CAI Yue-Penga，b①HE Guang-PingaCAI YicZHANG Chia SU Cheng-Yongb KANG Bei-Shengb a (Department of Chemistry，South China Normal University，Guangzhou 510631，China) b (School of Chemistry and Chemical Engineering，Sun Yet-sen University，Guangzhou 510275，China) c (School of Pharmacaceutical Sciences，Anhui College of Traditional Chinese Medicine，Hefei 230038，China) |
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| 摘 要： | 1 INTRODUCTION Crystal engineering of supramolecular arrays hasbeen one of the most important areas of researchwith wide implications for the rational design offunctional materials1]. Two major directions2] havebeen actively pursued: the construction of organicnetworks consolidated by directional non-covalentinteractions3] and that of coordination polymers sus-tained by coordinated covalent bonds4, . One of the 5]most remarkable developm…
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| 关 键 词： | 合成方法 晶体结构 1 4 双-（苯三唑-1-甲基）-2 3 5 6-四甲基苯 分子排列 |
Synthesis and Crystal Structure of 1,4-Bis(benztriazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene |
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| CAI Yue-peng,HE Guang-Ping,CAI Yi,ZHANG Chi,SU Cheng-yong,KANG Bei-sheng.Synthesis and Crystal Structure of 1,4-Bis(benztriazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene[J].Chinese Journal of Structural Chemistry,2005,24(3):279-282. |
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| Authors: | CAI Yue-peng HE Guang-Ping CAI Yi ZHANG Chi SU Cheng-yong KANG Bei-sheng |
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| Abstract: | The title compound 1,4-bis(benztriazol-1-ylmethyl)-2,4,5,6-trimethylbenzene crystallizes in the monoclinic system, space group Pbca with a = 9.842(5), b = 9.455(5), c = 22.165(12)(A), V = 2062.6(18) (A)3, Dc = 1.277 g/cm3, Z = 4, C24H24N6, Mr = 396.49, μ(MoKa) = 0.079 mm-1 and F(000) = 840. The structure was refined to R = 0.0662 and Wr = 0.1891 for 1163 observed reflections (I > 2((I)). The title molecule has trans-conformation about the central phenyl ring. The zigzag-like molecules are connected by face-to-faceπ…π stacking to form an infinite 2D layer. |
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| Keywords: | 1 4-bis(benztriazol-1-ylmethyl)-2 4 5 6-trimethylbenzene synthesis crystal structure face-to-face π…π interaction 2D layer |
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