Microwave Assisted Conversion of Oximes and Semicarbazones to Carbonyl Compounds Using Benzyltriphenylphosphonium Peroxymonosulfate |
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| Authors: | Abdol R Hajipour Shadpour E Mallakpour Iraj Mohammadpoor-Baltork Hadi Adibi |
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| Institution: | (1) Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran, IR;(2) Department of Chemistry, Isfahan University, Isfahan 81744, Iran, IR |
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| Abstract: | Summary. Benzyltriphenylphosphonium peroxymonosulfate in the presence of catalytic amounts of bismuth chloride was found to be an
efficient and mild reagent for the oxidative cleavage of oximes and semicarbazones to the corresponding carbonyl compounds
under microwave irradiation.
Corresponding author. E-mail: haji@cc.iut.ac.ir
Received March 4, 2002; accepted (revised) April 8, 2002 |
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| Keywords: | , Benzyltryphenylphosphonium peroxymonosulfate, Carbonyl compounds, Microwave irradiation, Oxime, Semicarbazone |
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