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Structure of Diacetato bis (2,4,6 Trimethyl Pyridine) Copper(II)
Authors:Annie Busnot,Florent Busnot,Andr   Leclaire,Maurice Bernard
Affiliation:Annie Busnot,Florent Busnot,André Leclaire,Maurice Bernard
Abstract:
(2.4.6 trimethyl pyridine)2 Cu(CH3COO)2 has been obtained as violet needles by slow evaporation. The crystals belong to the monoclinic system, space group P21/C with two molecules in a unit cell of dimension: a = 7.842 (1), b = 16.384 (2), c = 8.320 (2) Å, β = 101.91 (1)°. The structure was solved by heavy atom method and refined by a least squares method (R = 0.029). The coordination of copper is 4 + 2. The atom arrangements of this structure is very near to the copper acetate one solvated by one water molecule and two 3.4 dimethyl pyridine molecules.
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