S(N)Ar reactions of nitro-(pentafluorosulfanyl)benzenes to generate SF5 aryl ethers and sulfides |
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Authors: | Beier Petr Pastýříková Tereza Vida Norbert Iakobson George |
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Affiliation: | Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo na?m. 2, 166 10 Prague 6, Czech Republic. beier@uochb.cas.cz |
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Abstract: | Nucleophilic aromatic substitution of the nitro group of para- and meta-nitro-(pentafluorosulfanyl)benzene with alkoxides and thiolates generates a range of substituted 4- and 3-(pentafluorosulfanyl)benzenes in a single-step reaction. |
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