Crystal structure of mixed-ligand complexes of the Ni(II) heterospin bischelate withiso-butyl alcohol and 1,4-Butanediol |
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| Authors: | G. V. Romanenko V. N. Ikorskii S. V. Fokin V. I. Ovcharenko |
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| Affiliation: | (1) Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USSR;(2) International Tomography Center, Siberian Branch, Russian Academy of Sciences, USSR;(3) Novosibirsk State University, USSR |
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| Abstract: | The crystal structures of the mixed-ligand complexes of the heterospin bischelate bis [2,2,5,5-tetramethyl-l-oxyl-3-imidazoline-4-(3’,3’,3’-trifluoro-1’-propenyl-2’-oxiato)nickel(II) (NiL2) with iso-butanol and 1,4-butanediol NiL2(i-C4H9OH)2 and NiL2[HO(CH2)4OH], respectively, are determined. The crystal structure of the NiL2 complex with the normal butyl alcohol NiL2(n-C4H9OH)2 and the structure of CoL2[HO(CH2)4OH] are refined. Translated fromZhurnal Strukturnoi Khimii, Vol. 38, No. 5, pp. 930–945, September-October, 1997. |
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