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Synthesis and application of chiral N, N'-dialkylated cyclohexanedi- amine for asymmetric hydrogenation of aryl ketones |
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| Authors: | Meng Lin Ma Chuan Hong Rena Ya Jing Lva Hua Chen Xian Jun Lib a |
| Institution: | a Department of Chemistry, Xihua University, Chengdu 610039, China;b Key Lab of Green Chemistry and Technology, Ministry of Education, The Institute of Homogeneous Catalysis, Faculty of Chemistry, Sichuan University, Chengdu 610064, China |
| Abstract: | Chiral N, N'-dialkylated cyclohexanediamine derived ligands have been synthesized and used in the asymmetric hydrogenation of aryl ketones. Optically active alcohols with up to 90% enantiomeric excess were obtained in high yields. |
| Keywords: | Chiral diamine Aryl ketone Asymmetric hydrogenation Ruthenium complex |
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