| 单N-乙酸取代O2N2大环配体及其稀土配合物的合成与表征 |
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| 引用本文： | 张颖,吴杰颖,田玉鹏,倪诗圣.单N-乙酸取代O2N2大环配体及其稀土配合物的合成与表征[J].无机化学学报,2001,17(1):139-142. |
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| 作者姓名： | 张颖 吴杰颖 田玉鹏 倪诗圣 |
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| 作者单位： | [1]安徽大学化学化工学院，合肥２３００３９ [2]南京大学配位化学国家重点实验室，南京２１００９３ |
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| 基金项目： | 国家自然科学基金资助项目(No.29871001)及安徽省教委自然科学基金资助课题(No.2000JL001) |
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| 摘 要： |
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| 关 键 词： | 单N－乙酸取代氮氧杂大环配体 稀土配合物 表征 合成 |
| 收稿时间： | 2000/7/31 0:00:00 |
| 修稿时间： | 2000年7月31日 |
Synthesis and Characterization of Mono-N-Functionalized Diaza-Dioxa Macrocycle and its Rare Earth Complexes |
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| ZHANG Ying,WU Jie-Ying,TIAN Yu-Peng and NI Shi-Sheng.Synthesis and Characterization of Mono-N-Functionalized Diaza-Dioxa Macrocycle and its Rare Earth Complexes[J].Chinese Journal of Inorganic Chemistry,2001,17(1):139-142. |
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| Authors: | ZHANG Ying WU Jie-Ying TIAN Yu-Peng and NI Shi-Sheng |
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| Institution: | Department of Chemistry, Anhui University, Hefei 230039;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Department of Chemistry, Anhui University, Hefei 230039;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Department of Chemistry, Anhui University, Hefei 230039;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Department of Chemistry, Anhui University, Hefei 230039;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | Aseries of new rare earth complexes LnL(NO3)2·2H2O(Ln=La,Pr,Nd,Sm,Eu,Gd,Dy,Yb;L=1,2-diaza-3,4: 9,10-dibenzo-5,8-dioxyacyclopentadecane-N-acetic ion) were prepared. The complexes were characterized by elemental analysis, ICPmethod, IRspectra, 1H NMRand Molar conductance. It was found that the ether oxygen, carboxy oxygen and nitrogen atoms of the ligand are coordinated to the metal ion, as well as a free nitrate and coordianted nitrate ion in the complex. |
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| Keywords: | mono-N-acetic acid substituted characterization diaza-dioxa macrocycle rare earth complexes |
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