Copper(II)-catalyzed aerobic oxidation of primary alcohols to aldehydes in ionic liquid [bmpy]PF6 |
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Authors: | Jiang Nan Ragauskas Arthur J |
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Affiliation: | Department of Chemistry, Georgia Institute of Technology, Atlanta, GA 30332, USA. |
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Abstract: | A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the three-component system acetamido-TEMPO/Cu(ClO(4))(2)/DMAP in the ionic liquid [bmpy]PF(6) has been developed, and the catalysts can be recycled and reused for five runs without any significant loss of catalytic activity. [reaction: see text] |
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