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Copper(II)-catalyzed aerobic oxidation of primary alcohols to aldehydes in ionic liquid [bmpy]PF6
Authors:Jiang Nan  Ragauskas Arthur J
Affiliation:Department of Chemistry, Georgia Institute of Technology, Atlanta, GA 30332, USA.
Abstract:A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the three-component system acetamido-TEMPO/Cu(ClO(4))(2)/DMAP in the ionic liquid [bmpy]PF(6) has been developed, and the catalysts can be recycled and reused for five runs without any significant loss of catalytic activity. [reaction: see text]
Keywords:
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