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Impurity mediated mechanism of photorefractive effect in BaTiO3: A combination of sangster and piezoelectric effects
Authors:M D Sastry  M Moghbel  Putcha Venkateswarlu
Affiliation:(1) Radiochemistry Division, Bhabha Atomic Research Centre, 400 085 Trombay, Mumbai, India;(2) Department of Physics, Alabama A & M University, 35762 Normal, Alabama, USA
Abstract:
An impurity mediated mechanism of photorefractive effect in BaTiO3 is proposed. The photoinduced changes in the relative concentration of Fe3+ in BaTiO3 results in an electro-optic coupling through a combination of the Sangster and piezoelectric effects. This is based on the examination of the extensive results on the EPR of Fe3+ in the BaTiO3 lattice. This model explains the improved photorefractive behavior of BaTiO3 on doping with Co2+.
Keywords:Photorefractive effect  BaTiO3   Electron paramagnetic resonance of Fe3+ in BaTiO3
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