| Study on the Nanosized Amorphous Ru-Fe-B/ZrO2 Alloy Catalyst for Benzene Selective Hydrogenation to Cyclohexene |
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| 作者姓名： | Shouchang Liu Zhongyi Liu Shuhui Zhao Yongmei Wu Zheng Wang Peng Yuan |
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| 作者单位： | Shouchang Liu，Zhongyi Liu，Shuhui Zhao，Yongmei Wu，Zheng Wang，Peng Yuan Department of Chemistry，Zhengzhou University，Zhengzhou 450052，Henan，China |
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| 摘 要： | A novel nanosized amorphous Ru-Fe-B/ZrO2 alloy catalyst for benzene selective hydrogenation to cyclohexene was investigated. The superior properties of this catalyst were attributed to the combination of the nanosize and the amorphous character as well as to its textural character. In addition, the concentration of zinc ions, the content of ZrO2 in the slurry, and the pretreatment of the catalyst were found to be effective in improving the activity and the selectivity of the catalyst.
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| 关 键 词： | Ru-Fe-B/ZrO2非晶态催化剂 苯 选择性氢化反应 环己烯 |
| 收稿时间： | 2006-05-29 |
| 修稿时间： | 2006-07-31 |
Study on the Nanosized Amorphous Ru-Fe-B/ZrO2 Alloy Catalyst for Benzene Selective Hydrogenation to Cyclohexene |
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| Shouchang Liu Zhongyi Liu Shuhui Zhao Yongmei Wu Zheng Wang Peng Yuan.Study on the Nanosized Amorphous Ru-Fe-B/ZrO2 Alloy Catalyst for Benzene Selective Hydrogenation to Cyclohexene[J].Journal of Natural Gas Chemistry,2006,15(4):319-326. |
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| Authors: | Shouchang Liu Zhongyi Liu Shuhui Zhao Yongmei Wu Zheng Wang Peng Yuan |
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| Institution: | aDepartment of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, China |
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| Abstract: | A novel nanosized amorphous Ru-Fe-B/ZrO2 alloy catalyst for benzene selective hydrogenation to cyclohexene was investigated. The superior properties of this catalyst were attributed to the combination of the nanosize and the amorphous character as well as to its textural character. In addition, the concentration of zinc ions, the content of ZrO2 in the slurry, and the pretreatment of the catalyst were found to be effective in improving the activity and the selectivity of the catalyst. |
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| Keywords: | Ru-Fe-B/ZrO2 amorphous catalyst benzene selective hydrogenation cyclohexene |
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