Reactions of hexamethylditin and trimethyltin sulfide withN-thio-derivatives of phthalimide |
| |
Authors: | V I Shcherbakov I K Grigor'eva |
| |
Institution: | (1) Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600 Nizhnii Novgorod, Russian Federation |
| |
Abstract: | The initial formation of organotin derivatives with Sn-S-N bonds in heterolytic reactions of hexamethylditin or trimethyltin sulfide withN-(chlorothio)phthalimide is suggested. Subsequent interaction of these compounds with sulfenyl chloride affordsN, N-thioorN, N-dithiobisphthalimide. Homolytic reaction of hexamethylditin withN, N-dithiobisphthalimide also occursvia an organotin intermediate, which, in the absence of a nucleophilic reagent, eliminates sulfur and converts intoN-trimethylstannylphthalimide.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2111–2114, December, 1993. |
| |
Keywords: | hexamethylditin trimethyltin sulfide N-(chlorothio)phthalimide N N-dithiobisphthalimide" target="_blank">gif" alt="prime" align="BASELINE" BORDER="0">-dithiobisphthalimide reactivity |
本文献已被 SpringerLink 等数据库收录! |
|