Laser photolysis of 1-(4-nitrophenyl)-3-methylpyrazole and 1-ethyl-3-(4-nitrophenyl)-5-chloropyrazole |
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Authors: | K B Petrushenko G V Bozhenkov V I Smirnov |
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Institution: | (1) A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation |
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Abstract: | The spectral kinetic characteristics of the triplet states of 1-(4-nitrophenyl)-3-methylpyrazole (1) and 1-ethyl-3-(4-nitrophenyl)-5-chloropyrazole (2) were studied by the laser nanosecond photolysis technique in different solvents. The triplet lifetimes (τT) of molecules 1 and 2 were found to depend strongly on the solvent nature. An increase in τT by approximately two orders of magnitude on going from nonpolar and polar aprotic solvents (τT ≤ 15 ns) to aqueous-acetonitrile solutions (τT = 1100 ns for a volume acetonitrile to water ratio of 1 : 3) was analyzed, taking into account the influence of the medium
on the relative contribution of the n,π*- and π,π*-configurations to the lowest triplet state.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1115–1119, May, 2005. |
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Keywords: | 1-(4-nitrophenyl)-3-methylpyrazole 1-ethyl-3-(4-nitrophenyl)-5-chloropyrazole nanosecond laser photolysis triplet states lifetime solvent effect |
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