基于有机染料盐掺杂薄膜体系的能量转移及光致发光特性研究

利用稳态和时间分辨瞬态光谱研究了有机盐trans-4-［p-(N-ethyl-N-(hydroxyethyl)amino)phenylstyryl］-N-(hydroxyethyl)pyridinium iodide (ASPI)掺杂聚合物PVK(聚乙烯咔唑)薄膜体系的光致发光和能量转移特性. 在ASPI：PVK掺杂薄膜体系中，PVK的荧光强度与寿命随掺杂浓度的升高而降低，表明两者存在有效的Forster能量转移. 通过在相对低浓度的掺杂体系中加入适量高量子效率的Alq3作为能量转移过渡体，形成能量转移级 关键词： 有机染料盐 荧光光谱 荧光寿命 能量转移

Study of photoluminescence and energy transfer properties of an organic dye salt doped thin films

The photoluminescence and energy transfer properties based on an organic salt trans-4-［p-(N-ethyl-N-(hydroxylethyl)amino)phenylstyryl］-N-(hydroxyethyl)pyridinium iodide (ASPI) doped PVK thin film were investigated by steady-state and time-resolved fluorescent spectra. We observed that the emission intensity and the fluorescent lifetime of PVK reduced with increasing ASPI doping concentration due to the Forster energy transfer from PVK to ASPI, which is strongly correlated with an efficient spectral overlap between ASPI absorption and PVK emission. We also added some Alq3 into the doping system as energy carriers in order to increase the energy transfer efficiency from PVK to ASPI at low concentration, or there will be an evident decrease in photoemission efficiency due to the concentration quenching at high concentration. The dynamical process of energy transfer is discussed.