Formation and crystal structure of 1-methyl-2-phenylindolizine-3-acetonitrile |
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| Authors: | Weiwei Liu Song Ou Xiang He Hongwen Hu Qiangjin Wu Zixiang Huang |
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| Affiliation: | (1) Department of Chemistry, Nanjing University, Nanjing, 210093, People's Republic of China;(2) Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, People's Republic of China |
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| Abstract: | 1-Methyl-2-phenylindolizine-3-acetonitrile was unexpectedly obtained in the reaction of 1-methyl-2-phenylindolizine-3-thioaldehyde with cyanide ions. Its structure was determined by IR, 1H NMR, MS, elemental analyses, and X-ray crystallography. Colorless regular prism shaped crystals of C17H14N2 crystallize in the space group C2/c with cell dimensions a = 12.956(3) Å, b =10.516(2) Å, c = 20.429(4) Å, and  = 90°,  = 104.98(3)°,  = 90°, V =2688.7(9) Å3, Dcalc =1.217 Mg/m3, and Z = 8. |
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| Keywords: | Indolizine X-ray crystal structure cyanide ion |
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