| 3,5-二(吡啶-4-甲氧基)苯甲酸和芳香二羧酸配体构建的具有3,4-连接四重和三重穿插的d10金属配位聚合物 |
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| 引用本文： | 王桂仙,曹可利,王晓娟,冯云龙.3,5-二(吡啶-4-甲氧基)苯甲酸和芳香二羧酸配体构建的具有3,4-连接四重和三重穿插的d10金属配位聚合物[J].无机化学学报,2016,32(3):545-554. |
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| 作者姓名： | 王桂仙 曹可利 王晓娟 冯云龙 |
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| 作者单位： | 丽水学院化学与化工学院, 丽水 323000;浙江师范大学物理化学研究所, 金华 321004,浙江师范大学物理化学研究所, 金华 321004,浙江师范大学物理化学研究所, 金华 321004,浙江师范大学物理化学研究所, 金华 321004 |
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| 基金项目： | 国家自然科学基金(No.21173197)资助项目. |
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| 摘 要： | 以3,5-二(吡啶-4-甲氧基)苯甲酸(HL)与芳香二羧酸为配体,在水热条件下与Zn(Ⅱ)或Cd(Ⅱ)盐反应得到4个具有3,4-连接多重穿插结构的配位聚合物:Zn2L2(tdc)]n (1),{Zn4L4(Hhdc)2]·H2O}n (2),{Zn2L2(Hhdc)]·H2O}n (3),{Cd2L2(bdtc)(H2O)]·0.5H2O}n (4)(H2tdc=2,5-噻吩二甲酸,H3hdc=5-羟基间苯二甲酸,H2bdtc=1,4-苯二硫乙酸).晶体结构分析表明,聚合物1~3具有3,4-连接四重穿插的三维网络结构,拓扑符号分别为(4.82)(4.85) (1)、(63)(65.8) (2)和(63)(65.8) (3).4为3,4-连接三重穿插的二维平面结构,拓扑符号为(63)(66).测定了配位聚合物1、3和4的热稳定性和荧光性质.
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| 关 键 词： | 配位聚合物 3 5-二(吡啶-4-甲氧基)苯甲酸 晶体结构 荧光性质 |
| 收稿时间： | 2015/10/20 0:00:00 |
| 修稿时间： | 1/9/2016 12:00:00 AM |
Four-and Three-Fold Interpenetrated (3,4)-Connected d10 Metal Coordination Polymers Constructed by 3,5-Bis(pyridin-4-ylmethoxy)benzoic Acid and Aromatic Dicarboxylic Acid Ligands |
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| WANG Gui-Xian,CHEN Fei-Yan,WANG Xiao-Juan and FENG Yun-Long.Four-and Three-Fold Interpenetrated (3,4)-Connected d10 Metal Coordination Polymers Constructed by 3,5-Bis(pyridin-4-ylmethoxy)benzoic Acid and Aromatic Dicarboxylic Acid Ligands[J].Chinese Journal of Inorganic Chemistry,2016,32(3):545-554. |
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| Authors: | WANG Gui-Xian CHEN Fei-Yan WANG Xiao-Juan and FENG Yun-Long |
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| Institution: | Department of chemistry and chemical engineering, Lishui University, Lishui, Zhejiang 323000, China;Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China |
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| Abstract: | |
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| Keywords: | coordination polymer 3 5-bis(pyridin-4-ylmethoxy)benzoic acid crystal structure interpenetrating framework luminescent property |
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