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Synthesis of a phosphine-modified cyclodextrin and its rhodium complex
Authors:Manfred T Reetz  Joachim Rudolph
Institution:

Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1,45470 Mülheim/Ruhr, Germany

Abstract:A bidentate ligand consisting of a 2-(diphenylphosphinoethyl)-thio moiety was attached to β-cyclodextrin at the 6-position. The corresponding norbornadiene Rh(I) complex in the form of the BF4 salt was prepared.
Keywords:
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