Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2'-bipyrimidine-bridged cobalt(II) framework |
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| Authors: | Marino Nadia Mastropietro Teresa F Armentano Donatella De Munno Giovanni Doyle Robert P Lloret Francesc Julve Miguel |
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| Affiliation: | Dipartimento di Chimica, Università della Calabria, via P. Bucci 14/c, 87036, Rende, Cosenza, Italy. demunno@unical.it. |
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| Abstract: | ![]()
The three-dimensional cobalt(ii) compound of formula {[Co(2)(P(2)O(7))(bpym)(2)].12H(2)O}(n), where the pyrophosphate and 2,2'-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with T(c) = 19 K. |
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