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| 吡啶酰胺在Cd(Ⅱ)存在下的醇解反应及结构表征（英文） | |
| 引用本文： | 张俊勇,涂超,林骏,Hoong-Kun Fun,游效曾,郭子建.吡啶酰胺在Cd(Ⅱ)存在下的醇解反应及结构表征（英文）[J].无机化学学报,2002,18(6). |
| 作者姓名： | 张俊勇 涂超 林骏 Hoong-Kun Fun 游效曾 郭子建 |
| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京210093 2. X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, Penang 11800, Malaysia 3. X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, Penang 11800, Malaysia;Department of Chemistry, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand |
| 摘 要： | X-射线晶体结构分析表明,在90℃的水热条件下,N-(8-喹啉基)吡啶-3-酰胺在Cd2+的存在下发生醇解.醇解产物为8-氨基喹啉(HL1)和吡啶-3-羧乙酯(HL2),它们与Cd (Ⅱ)配位形成四方锥型化合物.该配合物为单斜晶系,空间群P21/c.a=18.1089(1)A,b=8.9986(1)A,c=19.3070(2)A,β=113.085(1)和Z=4. |
| 关 键 词： | 酰胺 晶体结构 水热合成 醇解 |
Structural Characterization for Alcoholysis of N-(8-Quinolyl)Pyridine-3-Carboxamide at the Presence of Cd (Ⅱ) |
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| Hoong-Kun Fun,Suchad Chantrapromma.Structural Characterization for Alcoholysis of N-(8-Quinolyl)Pyridine-3-Carboxamide at the Presence of Cd (Ⅱ)[J].Chinese Journal of Inorganic Chemistry,2002,18(6). | |
| Authors: | Hoong-Kun Fun Suchad Chantrapromma |
| Abstract: | X-ray structural characterization has shown that N-(8-quinolyl) pyridine-3-carboxamide (HL) undergoes analcoholysis at the presence of Cd (Il) under the hydrothermal conditions at 90°C. The alcoholized adducts,8-aminoquinoline (HL1) and pyridine-3-carboxylate ester (HL2), coordinated to Cd (Il) to give a square pyramidalcomplex which crystallized in the P21/c group with cell constants a = 18. 1089(1) A, b =8. 9986(1) A, c=19.3070(2)A, β=113.085(1) andZ=4. |
| Keywords: | amide crystal structure hydrothermal synthesis alcoholysis |
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