A (bpy)2Ru-coordinated dehydro[12]annulene with exotopically fused diimine binding sites |
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Authors: | Ott Sascha Faust Rüdiger |
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Institution: | Christopher Ingold Laboratories, Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, UK. |
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Abstract: | Synthesis and electronic properties of a dinuclear (bpy)(2)Ru(II) polypyridyl complex are described in which the bridging ligand consists of two dipyridophenazines fused to a formally antiaromatic dehydro12]annulene and where the electronic and electrochemical properties of the complex are markedly influenced by the cyclic all-carbon core. |
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