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| 1,2,4-三唑双席夫碱衍生物的合成及表征 | |
| 引用本文： | 张思行,武现丽,戴志鹏,廖新成,卢建莎. 1,2,4-三唑双席夫碱衍生物的合成及表征[J]. 有机化学, 2008, 28(6): 1111-1114 |
| 作者姓名： | 张思行 武现丽 戴志鹏 廖新成 卢建莎 |
| 作者单位： | 郑州大学化学系,化学生物学实验室,郑州,450052 |
| 摘 要： | 氨基均三唑硫醇1a～1b与1,2-二溴乙烷缩合制得双氨基三唑硫醚2a～2b, 2a～2b与芳香醛经缩合得相应的席夫碱3a1～3a5与3b1～3b7, 收率65%～80%. 所得席夫碱类新化合物的结构均经IR, 1H NMR, MS和元素分析确证. |
| 关 键 词： | 均三唑 硫醚 席夫碱 合成 |
| 收稿时间： | 2007-07-23 |
| 修稿时间： | 2007-07-23 |
Synthesis and Characterization of the Derivatives of 1,2,4-Triazole Bis-Schiff Base |
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| ZHANG,Si-Xing,WU,Xian-Li,DAI,Zhi-Peng,LIAO,Xin-Cheng,LUJian-Sha. Synthesis and Characterization of the Derivatives of 1,2,4-Triazole Bis-Schiff Base[J]. Chinese Journal of Organic Chemistry, 2008, 28(6): 1111-1114 |
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| Authors: | ZHANG Si-Xing WU Xian-Li DAI Zhi-Peng LIAO Xin-Cheng LUJian-Sha |
| Affiliation: | (Key Laboratory of Chemical Biology, Department of Chemistry, Zhengzhou University, Zhengzhou 450052) |
| Abstract: | A series of bis(amino-triazole) Schiff bases 3a1～3a5 and 3b1～3b7 were synthesized in yields of 65%～80% via the condensation of 4-amino-5-mercapto-1,2,4-triazole (1a～1b) with 1,2-dibromoethane to obtain 2a～2b followed by further condensation with aryl aldehydes in acetic acid. The structures of as-synthesized products were confirmed by FTIR, 1H NMR, ESI-MS spectra and elemental analysis. |
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