Synthesis, characterization and crystal structure determination of platinum(IV) complexes containing, bipyridine derivatives and chloride, [Pt(5,5′-dmbipy)Cl4] and [Pt(6-mbipy)Cl4] |
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Authors: | Vahid Amani Nasser Safari Hamid Reza Khavasi Mehmet Akkurt |
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Institution: | aDepartment of Chemistry, Shahid Beheshti University, G.C., Evin, Tehran 1983963113, Iran;bDepartment of Physics, Faculty of Arts and Sciences, Erciyes University, 38039 Kayseri, Turkey |
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Abstract: | The complex Pt(5,5′-dmbipy)Cl4] (1) (5,5′-dmbipy is 5,5′-dimethyl-2,2′-bipyridine) was prepared from the reaction of H2PtCl6·6H2O with 5,5′-dimethyl-2,2′-bipyridine in methanol. The same method was employed to make Pt(6-mbipy)Cl4] (2) (6-mbipy is 6-methyl-2,2′-bipyridine). Both complexes were characterized by elemental analysis, IR, UV–Vis, 1H NMR, 13C NMR and 195Pt NMR spectroscopy. Their solid state structures were determined by the X-ray diffraction method. |
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Keywords: | Pt(IV) 5 5′ -Dimethyl-2 2′ -bipyridine 6-Methyl-2 2′ -bipyridine Crystal structure |
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