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| 含双二苯基膦甲烷铜(Ⅰ)配合物的研究进展 | |
| 引用本文： | 刘应凡,谢青,朱雁,杨瑞娜,邢利平,金斗满. 含双二苯基膦甲烷铜(Ⅰ)配合物的研究进展[J]. 无机化学学报, 2002, 18(3): 223-232 |
| 作者姓名： | 刘应凡 谢青 朱雁 杨瑞娜 邢利平 金斗满 |
| 作者单位： | 1. 河南师范大学化学与环境科学学院,新乡,453002 2. 国家林业局泡桐研究中心 3. 河南化学研究所,郑州,450002 4. 南京大学配位化学国家重点实验室,南京,210093 |
| 基金项目： | 国家自然科学基金资助项目(No.29871009)，河南省杰出青年基金(No.9910)，河南省自然科学基金资助项目 |
| 摘 要： | 本文概述了含双二苯基膦甲烷铜(Ⅰ)配合物的化学进展,总结了配合物的合成方法:置换法、还原法、电化学方法和直接加成法,全面论述了双核、三核、多核和异核配合物的结构特征,探讨了该类配合物的重要荧光性质。 |
| 关 键 词： | 铜 双二苯基膦甲烷 配合物 |
| 修稿时间： | 2001-09-10 |
Advances of Copper (Ⅰ) Complexes Containing Bis(diphenylphosphine)methane |
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| LIU Ying-Fan,XIE Qing,ZHU Yan,YANG Rui-N,XING Li-Ping and JIN Dou-Man. Advances of Copper (Ⅰ) Complexes Containing Bis(diphenylphosphine)methane[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(3): 223-232 | |
| Authors: | LIU Ying-Fan XIE Qing ZHU Yan YANG Rui-N XING Li-Ping JIN Dou-Man |
| Affiliation: | College of Chemistry and Environmental Science, Henan Normal Universistry,Xinxiang 453002,Henan Institute of Chemistry,Zhengzhou 450002,Henan Institute of Chemistry,Zhengzhou 450002,Henan Institute of Chemistry,Zhengzhou 450002,College of Chemistry and Environmental Science, Henan Normal Universistry,Xinxiang 453002 and State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210093 |
| Abstract: | This article outlined elementary developments of copper? complexes containing bis(diphenylphosphine)methane. It summarized four synthetic methods including replacement, reduction, electrochemical and addition method, and the discussions for the structural characterizations of binuclear, trinuclear, polynuclear and isonuclear complexes were also included. Finally, important fluorescent characterization was shown especially. |
| Keywords: | copper bis(diphenylphosphine)methane complexes |
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