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Defect‐Controlled Preparation of UiO‐66 Metal–Organic Framework Thin Films with Molecular Sieving Capability |
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| Authors: | Caiqin Zhang Yajing Zhao Yali Li Prof. Xuetong Zhang Prof. Lifeng Chi Prof. Guang Lu |
| Affiliation: | 1. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano and Soft Materials (FUNSOM) and, Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, China;2. Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, China |
| Abstract: | Metal–organic framework (MOF) UiO‐66 thin films are solvothermally grown on conducting substrates. The as‐synthesized MOF thin films are subsequently dried by a supercritical process or treated with polydimethylsiloxane (PDMS). The obtained UiO‐66 thin films show excellent molecular sieving capability as confirmed by the electrochemical studies for redox‐active species with different sizes. |
| Keywords: | metal– organic frameworks molecular sieving porous materials thin films |