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Primary amido substituted diborane4 compounds and imidodiborate4 anions |
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| Authors: | Baber R Angharad Charmant Jonathan P H Cook Alistair J R Farthing Natalie E Haddow Mairi F Norman Nicholas C Orpen A Guy Russell Christopher A Slattery John M |
| Institution: | University of Bristol, School of Chemistry, Bristol BS8 1TS, UK. |
| Abstract: | Treatment of the diborane(4) compound B(2)(NMe(2))(4) with aniline or 2,6-dimethylaniline results in the primary amido compounds B(2)(NHR)(4)(R = Ph, 2,6-Me(2)C(6)H(3)); subsequent treatment with n-BuLi in toluene in each case affords the first examples of anionic imidodiborates namely Li(4)(thf)(6)B(2)(NPh)(4) and Li(4)(thf)(4)B(2)(N-2,6-Me(2)C(6)H(3))(4); all complexes have been characterised crystallographically. |
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