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Vanadium-doped MgAl2O4 crystals as white light source
Authors:Yutaka Fujimoto  Hiroaki Tanno  Shigetomo Yoshida  Masanobu Shirai  Kouichirou Tanaka  Yutaka Kawabe  Eiichi Hanamura
Institution:a Chitose Institute of Science and Technology, 758-65 Bibi, Chitose 066-8655, Japan
b Japan Science and Technology Corporation, 758-65 Bibi, Chitose 066-8655, Japan
c Department of Physics, Kyoto University, Kyoto 606-8224, Japan
Abstract:Spinel MgAl2O4 crystals doped with transition metals show charge-transfer transitions for Ti:MgAl2O4 on one hand and multiplet transitions of (3d)-electrons for Mn:, Fe:, and Co:MgAl2O4 on the other hand. We will show that optical responses of V:MgAl2O4 are closer to those of Ti:MgAl2O4 and also that white emission spectrum is observed. The microscopic process of the white emission is also proposed.
Keywords:51  20  +d  81  10  Fq  42  55  Rz
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