Ti-catalyzed reactions of 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene with various electrophiles |
| |
| Authors: | Chahinez Aouf Michel Giorgi |
| |
| Affiliation: | a Laboratoire de Synthèse Organique, UMR CNRS 6180, 13397 Marseille Cedex 20, France
b Spectropôle, Faculté des Sciences de St-Jérôme, Aix-Marseille Université, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France |
| |
| Abstract: | Reductive disilylation (Li + Me3SiCl − THF) of 1,3-cyclohexadiene led to 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene (1). In the presence of TiCl4 in dichloromethane, 1 reacted with some acyl chlorides, anhydrides, and aldehydes to give tricyclo[7.4.0.03,8]trideca-4,12-diene-2-yl derivatives. |
| |
| Keywords: | Reductive silylation 1,3-Cyclohexadiene Titanium tetrachloride Electrophilic substitution |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
