High yield thiolation of iodobenzene catalyzed by the phosphinite nickel PCP pincer complex: [NiCl{C6H3-2,6-(OPPh2)2}] |
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| Authors: | Valente Gómez-Benítez |
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| Institution: | Instituto de Química, Universidad Nacional Autónoma de México, Cd. Universitaria, Circuito Exterior, Coyoacán, 04510 México DF, México |
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| Abstract: | NiCl{C6H3-2,6-(OPPh2)2}] efficiently catalyzes the thiolation of iodobenzene with a broad scope of disulfides in the presence of zinc, the coupled products are obtained in excellent and in many cases nearly quantitative yields. |
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| Keywords: | C-S cross-coupling Phosphinite ligands Homogeneous catalysis Nickel Pincer complexes Thiolation |
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