Heterocycloaddition of thermally generated 1,2-diaza-1,3-butadienes to [60]fullerene |
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Authors: | Hai-Tao Yang Yu Xu Jin-Chang Huang |
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Institution: | Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China |
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Abstract: | Stable C60-fused tetrahydropyridazine derivatives were synthesized through the hetero-Diels-Alder cycloaddition of C60 with 1,2-diaza-1,3-butadienes, which were generated in situ by the thermal extrusion of sulfur dioxide from 2,5-dihydro-1,2,3-thiadiazole-1,1-dioxides. |
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Keywords: | [60]Fullerene Hetero-Diels-Alder reaction 1 2-Diaza-1 3-butadienes |
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