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Heterocycloaddition of thermally generated 1,2-diaza-1,3-butadienes to [60]fullerene
Authors:Hai-Tao Yang  Yu Xu  Jin-Chang Huang
Institution:Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China
Abstract:Stable C60-fused tetrahydropyridazine derivatives were synthesized through the hetero-Diels-Alder cycloaddition of C60 with 1,2-diaza-1,3-butadienes, which were generated in situ by the thermal extrusion of sulfur dioxide from 2,5-dihydro-1,2,3-thiadiazole-1,1-dioxides.
Keywords:[60]Fullerene  Hetero-Diels-Alder reaction  1  2-Diaza-1  3-butadienes
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