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Synthesis and different molecular recognition of two dye-modified cyclodextrins with spacer of different length
Authors:Tetsuo Kuwabara  Kazuyo Shiba  Mayumi Ozawa  Naoya Miyajima  Yasutada Suzuki
Institution:Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, 4 Takeda, Kofu 400-8511, Japan
Abstract:Two β-cyclodextrin derivatives (1 and 2) bearing a hydroxyazobenzene unit, each having a butylene or a 4,7-dioxadecylene spacer between the cyclodextrin and the dye, were prepared, which showed guest-induced color changes with a marked difference in molecular recognition behavior in aqueous solution.
Keywords:Cyclodextrin  Molecular recognition  Dye  Inclusion complex  Color change
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