A mild, rapid and highly regioselective ring-opening of epoxides and aziridines with acetic anhydride under solvent-free conditions using ammonium-12-molybdophosphate |
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| Authors: | Biswanath Das V Saidi Reddy Fouzia Tehseen |
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| Institution: | Organic Chemistry Division-1, Indian Institute of Chemical Technology, Hyderabad 50007, India |
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| Abstract: | A highly regioselective ring opening of epoxides and aziridines can be carried out efficiently with acetic anhydride to form the acetates of the corresponding 1,2-diols and 2-amino-alcohols, respectively, using ammonium-12-molybdophosphate (AMP) as a heterogeneous catalyst, at room temperature, in the absence of solvent. |
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| Keywords: | Epoxide Aziridine Acetic anhydride Ammonium-12-molybdophosphate Regioselectivity |
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