Highly efficient two-step selective synthesis of 2,6-dimethylnaphthalene |
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Authors: | Byung Hyun Kim |
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Institution: | School of Chemical and Biological Engineering, Seoul National University, Seoul 151-744, Republic of Korea |
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Abstract: | 2,6-Dimethylnaphthalene (2,6-DMN), a key raw material for poly(ethylene naphthalate) (PEN), was selectively synthesized via a two-step process in an overall 66% yield from commercially available 4-bromotoluene and 3-methyl-3-buten-1-ol. The ligand-free Heck reaction of the starting materials produced γ-(p-tolyl)-substituted aldehyde that was cyclized with an acid to give 2,6-DMN after in situ oxidation. No other isomers of 2,6-DMN were found. |
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Keywords: | 2 6-Dimethylnaphthalene Heck reaction Aromatic electrophilic cyclodehydration In situ oxidation |
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