Dienyne RCM/Diels-Alder approach for the construction of novel steroid-like polycyclic systems |
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Authors: | Marí a José Aldegunde |
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Affiliation: | Departamento de Química Orgánica e Unidade Asociada ó CSIC, Facultade de Química, Universidade de Santiago, 15782 Santiago de Compostela, Spain |
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Abstract: | Our studies directed towards the preparation of novel steroid-like derivatives using RCM reactions are described. The strategy here described was applied to the construction of novel ring-inserted skeleton-expanded steroid analogs by combination of tandem ring-closing metathesis of lineal dienynes and Diels-Alder reaction. |
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